New PDF release: AOP considered harmful

By Constantinides Constantinos

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44 K/s (curves 1–4, respectively). The inset shows the Arrhenius plot of TSDC for curve 1. , it is readily seen that a thermal gradient of 5 K in a sample leads to a relative error ΔE/E less than 3% at 300 K). It is, however, somewhat limited because use of only the initial part of the curve is permitted, which may force one into the region where the uncertainty in background current is important. On the other hand, the method is still applicable for overlapping relaxation even if it cannot be isolated by cleaning, provided that a series of partial heating, each separated by rapid cooling, is performed up to gradually increasing temperatures that span the whole temperature range of the spectrum.

As a result, the peak increases and shifts to a higher temperature. In fact, both peaks, M1 and M2, change with heating rate in a similar manner, but only the first has its temperature location (Tm) dependent on the values of Et and γNv at the given heating rate. Such behavior of the TSDC peak is typical. On the other hand, the DC conductivitydetermined relaxation peak shifts to lower temperatures when the band gap and/or preexponential factor decreases (Figs. 3). 6 eV if the dielectric relaxation peak locates close to the room temperature.

For TSDC in SbxSe1Ϫx alloys, we have three peaks M1, M2, and M3, whose temperatures TM1, TM2, and TM3 (145, 175, and 195 K, respectively) are close enough to each other that they overlap (Fig. 8). The TSDC method allows the easy and quick resolution of the overall spectrum, in our case peaks 1, 2, and 3. There are two ways in which this can be done. 85 samples (1). Curves 2–5—polarized samples were heated under applied DC voltage to the temperatures shown by arrows. 8 TSDC spectra of SbxSe1Ϫx. 05 (3).

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AOP considered harmful by Constantinides Constantinos

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